NNI-1型C_5/C_6烷烃异构化催化剂长周期运行分析及建议

中国石化海南炼油化工有限公司0.2 Mt/a C5/C6烷烃异构化装置以连续重整装置的拔头油为原料,使用NNI-1催化剂,采用一次通过流程,不设脱异戊烷塔和稳定塔,经设在连续重整装置内的脱丁烷塔稳定处理后作为汽油调合组分。该装置于2006年9月开工投产,截至2015年3月已连续运行3个周期。长周期运行分析结果表明:前两个周期中NNI-1催化剂具有较高的异构化活性及选择性,C5异构化率为60%左右,C6异构化率为80%左右,C6选择性为15%左右,产品辛烷值基本达到技术指标要求(RON≥78);而在第三周期运行中,催化剂积炭增加等原因导致其异构化活性及选择性降低,异构化产品辛烷值提升能力呈现逐步衰减的趋势,提高反应苛刻度已不能弥补催化剂活性下降造成的产品辛烷值降低。为保证装置长周期运行,建议择机停工对催化剂进行再生,或是直接换用与装置原料性质匹配的异构化催化剂。     

A novel utilized method of tar derived from biomass gasification for fabricating binder-free all-solid-state hybrid supercapacitors

As an industrial pollutant, tar derived from biomass gasification is used as the precursor for fabricating a novel carbon-metal hydroxides composite electrode. A slurry (the mixture of tar, KOH and melamine) is daubed uniformly onto the nickel foam, which is directly carbonized to form NPC@LDH electrode material. This electrode is further coated with NiCo-LDH nanosheets using an electrodeposition method to form NF@NPC@LDH. The newly made NF@NPC@LDH electrode exhibits a high specific capacity of 9.6 F cm⁻² at a current density of 2 mA cm⁻² and good rate performance (55.3% retention). Furthermore, a hybrid NF@NPC@LDH//NF@PC all-solid-state supercapacitor is fabricated, and the device exhibits high energy density of 1.28 mWh cm⁻³ at a power density of 8.04 mW cm⁻³, low resistance and good cycling stability.     

偶氮聚合物光存储研究进展

着重阐明了偶氮聚合物光存储纪录的原理,分析了其双折射特性的微观机制,介绍了该课题近年来实验和理论上的最新进展,对这一充满希望和挑战的多学科交叉研究专题作了展望。     

Skeletal Isomerization and Inter—molecular Hydrogen Transfer Reactions in Catalytic Cracking

Bimolecular hydrogen transfer and skeletal isomerization the important secondary reac-tions among catalytic cracking reactions,which affect product yield distribution and product quality,Catalyst properties and operating parameters have great impact on bimolecular hydrogen transfer and skeletal isomerization reactions .Bimolecular hydrogen transfer activity and skeletal isomrization activity of USY-containing catalysts are higher thn that of ZSM-5-containing catalyst.Coke deposition on the active sites of catalyst may suppress bimolecular hydrogen transfer activity and skeletal isomer-ization activity of catlys in different degrees.Short raction time causes a decrease of hydrogen trans-fer reaction,but and increase of skeletal isomerization reaction compared to cracking reaction in catalytic cracking process.     

NGO-Ⅲ催化剂的异构化性能评价

直馏汽油非临氢高效异构化使用最新一代NGO－Ⅲ型催化剂，生产的产品汽油辛烷值、产品收率及催化剂稳定性等全面超过现用的工业催化剂，达到目前国内同类产品的领先水平。     

Synthesis of unsaturated polyesters of increased solubility in styrene

The present study presents the synthesis of unsaturated polyester resins using only one glycol i.e., ethylene glycol. Polyesters of inorganic solubility in styrene were prepared. Properties of the resins in the noncrosslinked state in the process of crosslinking and after curing were studied. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3143–3150, 2006     

沸石孔结构对1-己烯异构化性能的影响

采用1-己烯为原料,对硅铝比相近、不同孔结构的沸石在脉冲微反装置上进行了评价试验,考察了FCC条件下沸石孔结构对烯烃异构化性能的影响。结果表明,大孔径的Y型沸石具有良好的异构化性能,异构化能力由强到弱的排列顺序为Y>β>ZRP>丝光沸石>镁碱沸石。     

金刚烷最新研究

金刚烷是近 30年来发展起来的一种新型精细化工原料。简要介绍了金刚烷的分子结构、性质及其主要用途 ,重点对近年来国内外报道过的金刚烷合成方法进行了评述 ,在此基础上指出了金刚烷化工的未来发展趋势。     

从细线化汉字图像生成任意倍率汉字

本文提出了一种对汉字作任意倍率放缩的算法。该算法先对印刷体汉字作细线化处理，抽取笔划特征点。然后，分割和提取笔划。任意倍率汉字生成是通过变换函数。改变特征点位置，再附加原探察到的笔划修饰来实现的。实验表明本算法是有效的。     

发生在北美的合成内燃机油定义之争

加氢异构化油是不是合成油?简述了20世纪90年代末重新激活的合成油定义之争、NAD的裁决以及该裁决对各润滑油公司和合成基础油市场的影响.